PDF下载 +分享

微信公众号：大豆科学

[1]李川,万新军,任玉洁,等.固体碱K2CO3/NaX催化制备大豆生物柴油的研究[J].大豆科学,2014,33(01):110-113.[doi:10.11861/j.issn.1000-9841.2014.01.0110]
　LI Chuan,WAN Xin-jun,REN Yu-jie,et al.Preparation of the Soybean Biodiesel by K2CO3/NaX Solid Base[J].Soybean Science,2014,33(01):110-113.[doi:10.11861/j.issn.1000-9841.2014.01.0110]

点击复制

固体碱K₂CO₃/NaX催化制备大豆生物柴油的研究

《大豆科学》[ISSN:1000-9841/CN:23-1227/S] 卷: 第33卷期数: 2014年01期页码: 110-113 栏目: 出版日期: 2014-02-25

Title:: Preparation of the Soybean Biodiesel by K₂CO₃/NaX Solid Base

文章编号:: 1000-9841（2014）01-0110-04

作者:: 李川; 万新军; 任玉洁; 周菁; 陈洁; 刘敏; 巢湖学院化学化工与生命科学学院，安徽巢湖 238000

Author(s):: LI Chuan; WAN Xin-jun; REN Yu-jie; ZHOU Jing; CHEN Jie; LIU Min; College of Chemical Engineering and Life Sciences,Chaohu University,Chaohu 238000,China

关键词:: 固体碱; 大豆油; 生物柴油; 酯交换

Keywords:: Solid base; Soybean oil; Biodiesel; Transesterification

分类号:: TE667

DOI:: 10.11861/j.issn.1000-9841.2014.01.0110

文献标志码:: A

摘要:: 以等体积浸渍法制备了K₂CO₃/NaX负载型固体碱催化剂，用于催化大豆油酯交换反应制备甲酯生物柴油。考察K₂CO₃负载量、反应时间、反应温度、催化剂用量和醇油摩尔比对酯交换转化率的影响，并通过单因素试验确定了最佳反应条件。结果表明：在K₂CO₃负载量25%、反应时间3 h、反应温度60℃、催化剂用量3%和醇油摩尔比14 ∶1的条件下，酯化率达86.4%。

Abstract:: The supported solid base catalyst K₂CO₃/NaX was prepared by isovolumetric impregnation,and methyl ester biodiesel was prepared from soybean oil by transesterification with this catalyst.Factors that affected the conversion likeK₂CO₃ loading,reaction time,reaction temperature,catalyst rate,molar ratio of methanol to oil were investigated,and the optimal reaction condition was analyzed by single-factor experiments.The results showed that under the conditionsK₂CO₃loading 25%,reaction time 3 h,reaction temperature 60℃,catalyst rate 3%,molar ratio of methanol to oil 14：1,the esterification rate could reach 86.4%.

参考文献/References:

[1]李红,汪洋,李刚.碱催化下大豆生物柴油的制备研究[J].大豆科学,2010,29(6):1052-1055.(Li H,Wang Y,Li G.Preparation of the soybean biodiesel catalyzed by alkali[J].Soybean Science,2010,29(6):1052-1055.)

[2]Xie W L,Huang X M,Li H T.Soybean oil methyl esters preparation using NaX zeolites loaded with KOH as a heterogeneous catalyst[J].Bioresource Technology,2007,98：936-939.

[3]周玉杰,张建安,武海棠,等.分子筛微波辐射负载CaO催化合成生物柴油[J].化学工程,2009,37(7):59-61.(Zhou Y J,Zhang J A,Wu H T,et al.Synthesis of biodiesel catalyzed by CaO supported on molecular sieve prepared by microwave[J].Chemical Engineering(China),2009,37(7):59-61.)

[4]邹华生,雷敏,李剑.超声场中钙基固体碱催化猪油制备生物柴油[J].华南理工大学学报（自然科学版）,2012,40(9):8-13.(Zou H S,L M,Li J.Biodiesel production from lard catalyzed by calcium-based solid base in ultrasonic field[J].Journal of South China University of Technology(Natural Science Edition),2012,40(9):8-13.)

[5]魏瑞平,徐波,肖国民.K₂CO₃/γ-Al₂O₃催化棕榈油和甲醇酯交换制备生物柴油[J].生物加工过程,2010,8(6):10-14.(Wei R P,Xu B,Xiao G M.Transesterification of palm oil with methanol to biodiesel over K₂CO₃/γ-Al₂O₃?catalyst[J].Chinese Journal of Bioprocess Engineering,2010,8(6):10-14.)

[6]颜姝丽,鲁厚芳,姜利寒,等.固体碱催化剂用于油脂甲醇酯交换反应制备生物柴油[J].化工学报,2007,58(10):2506-2512.(Yan S L,Lu H F,Jiang L H,et al.Solid base catalysts for transesterification of oil with methanol to produce biodiesel[J].Journal of Chemical Industry and Engineering,2007,58(10):2506-2512.)

[7]张守花,张新海,张洪浩.K₂O/Ti-HMS固体碱催化大豆油制备生物柴油[J].大豆科学,2010,29(6):1043-1046.(Zhang S H,Zhang X H,Zhang H H.K₂O/Ti-HMS solid base of soybean oil catalyzed biodiesel oil[J].Soybean Science,2010,29(6):1043-1046.)

[8]姜绍通,蔡静,潘丽军,等.生物柴油的K₂CO₃负载水滑石催化制备工艺[J].农业机械学报,2009,40(4):102-106.(Jiang S T,Cai J,Pan L J，et al.Preparation technology of biodiesel using K₂CO₃loaded hydrotalcite catalyst[J].Transactions of the Chinese Society for Agricultural Machinery,2009,40(4):102-106.)

[9]李琳,刘雅敏,买楠,等.K₂CO₃/γ-Al₂O₃催化菜籽油酯交换合成生物柴油[J].石油化工,2007,36(9):896-900.(Li L,Liu Y M,Mai N,et al.Synthesis of biodiesel-oil from rapeseed oil by transesterification over K₂CO₃/γ-Al₂O₃?catalyst[J].Petrochemical Technology,2007,36(9):896-900.)

[10]邹华生,李剑,陈文标.超声辅助固体碱催化酯交换反应制备生物柴油[J].华南理工大学学报（自然科学版）,2011,39(11):6-11.(Zou H S,Li J,Chen W B.Ultrasonic-enhanced preparation of biodiesel via?transesterification catalyzed by solid base[J].Journal of South China University of Technology(Natural Science Edition),2011,39(11):6-11.)

[11]黄艳芹.新型固体碱催化大豆油制备生物柴油的工艺研究[J].大豆科学,2011,30(4):668-671.(Huang Y Q.Preparation of biodiesel from soybean oil catalyzed by new solid basic catalyst[J].Soybean Science,2011,30(4):668-671.)

[12]李娜,李会鹏.负载型固体酸催化合成生物柴油[J].化学工业与工程,2012,29(2):74-78.(Li N,Li H P.Application of supported solid acid catalysts for biodiesel production[J].Chemical Industry and Engineering,2012,29(2):74-78.)

[13]李会鹏,姜玉琦,赵华.介孔分子筛负载HPWA催化合成生物柴油[J].工业催化,2010,18(8):56-60.(Li H P,Jiang Y Q,Zhao H.Synthesis of biodiesel catalyzed by HPWA/SBA-15 mesoporous zeolite[J].Industrial Catalysis,2010,18(8):56-60.)

相似文献/References:

[1]蔡燕,周红波,朱金丽.低豆粕用量下脂肪氧合酶好氧催化大豆油的反应研究[J].大豆科学,2013,32(05):683.[doi:10.11861/j.issn.1000-9841.2013.05.0683]
　CAI Yan,ZHOU Hong-bo,ZHU Jin-li.Aerobic Catalyzed Lipoxygenation of Soybean Oil with Low Level Soymeal[J].Soybean Science,2013,32(01):683.[doi:10.11861/j.issn.1000-9841.2013.05.0683]
[2]黄艳芹.新型固体碱催化大豆油制备生物柴油的工艺研究[J].大豆科学,2011,30(04):668.[doi:10.11861/j.issn.1000-9841.2011.04.0668]
　HUANG Yan-qin.Preparation of Biodiesel from Soybean Oil Catalyzed by New Solid Basic Catalyst[J].Soybean Science,2011,30(01):668.[doi:10.11861/j.issn.1000-9841.2011.04.0668]
[3]张秋云,吴祖志,王译婕,等.固体碱KF/CuAl-LDOs催化制备生物柴油工艺的研究[J].大豆科学,2011,30(05):861.[doi:10.11861/j.issn.1000-9841.2011.05.0861]
　ZHANG Qiu-yun,WU Zu-zhi,WANG Yi-jie,et al.Synthesis of Biodiesel by KF/CuAl-LDOs Solid Base[J].Soybean Science,2011,30(01):861.[doi:10.11861/j.issn.1000-9841.2011.05.0861]
[4]张新海,张守花.大豆油酯化催化剂负载型K2O固体碱的制备及性能研究[J].大豆科学,2011,30(06):1027.[doi:10.11861/j.issn.1000-9841.2011.06.1027]
　ZHANG Xin-hai,ZHANG Shou-hua.Preparation and Performance of Soybaen Oil Esterification Catalyst with Supported Solid Base K2O[J].Soybean Science,2011,30(01):1027.[doi:10.11861/j.issn.1000-9841.2011.06.1027]
[5]张守花,张新海,张洪浩.K2O/Ti-HMS固体碱催化大豆油制备生物柴油[J].大豆科学,2010,29(06):1043.[doi:10.11861/j.issn.1000-9841.2010.06.1043]
　ZHANG Shou-hua,ZHANG Xin-hai,ZHANG Hong-hao.K2O/Ti-HMS Solid Base of Soybean Oil Catalyzed Biodiesel Oil[J].Soybean Science,2010,29(01):1043.[doi:10.11861/j.issn.1000-9841.2010.06.1043]
[6]李红,汪洋,李刚.碱催化下大豆生物柴油的制备研究[J].大豆科学,2010,29(06):1052.[doi:10.11861/j.issn.1000-9841.2010.06.1052]
　LI Hong,WANG Yang,LI Gang.Preparation of the Soybean Biodiesel Catalyzed by Alkali[J].Soybean Science,2010,29(01):1052.[doi:10.11861/j.issn.1000-9841.2010.06.1052]
[7]孙玉秋,陈波水,方建华,等.大豆油及其生物柴油低温流动特性研究[J].大豆科学,2009,28(02):314.[doi:10.11861/j.issn.1000-9841.2009.02.0314]
　SUN Yu-qiu,CHEN Bo-shui,FANG Jian-hua,et al.Cold Flow Properties of Soybean Oil and Its Biodiesel[J].Soybean Science,2009,28(01):314.[doi:10.11861/j.issn.1000-9841.2009.02.0314]
[8]曾红舟,蒋惠亮,郭宏珍.强碱催化大豆油酯交换制备生物柴油[J].大豆科学,2007,26(04):583.[doi:10.3969/j.issn.1000-9841.2007.04.025]
　ZENG Hong-zhou,JIANG Hui-liang,GUO Hong-zhen.ALKALI-CATALYZED TRANSESTERIFICATION OF SOYBEAN OIL FOR PRODUCTION OF BIODIESEL[J].Soybean Science,2007,26(01):583.[doi:10.3969/j.issn.1000-9841.2007.04.025]
[9]李万林,钟姣姣,冯巩,等.大豆油中植物甾醇提取工艺及抗氧化活性研究[J].大豆科学,2014,33(05):731.[doi:10.11861/j.issn.1000-9841.2014.05.0731]
　LI Wan-lin,ZHONG Jiao-jiao,FENG Gong,et al.Extraction Process and Antioxidative Activity of Phytosterol in Soybean Oil[J].Soybean Science,2014,33(01):731.[doi:10.11861/j.issn.1000-9841.2014.05.0731]
[10]曹秀丽,王赛丹,李肖,等.响应面试验优化大豆油甲酯合成工艺[J].大豆科学,2017,36(01):124.[doi:10.11861/j.issn.1000-9841.2017.01.0124]
　CAO Xiu-li,WANG Sai-dan,LI Xiao,et al.Optimal Synthesis of Soybean Oil Methyl Ester by Response Surface Methodology[J].Soybean Science,2017,36(01):124.[doi:10.11861/j.issn.1000-9841.2017.01.0124]

备注/Memo

基金项目：2012年地方高校国家级大学生创新创业训练计划项目（201210380011）。

第一作者简介：李川（1985-），男，硕士，助教，主要从事生物质能源化工的研究。E-mail：lichuan2008hf@126.com。

更新日期/Last Update: 2014-08-04