[1]黄艳芹.新型固体碱催化大豆油制备生物柴油的工艺研究[J].大豆科学,2011,30(04):668-671.[doi:10.11861/j.issn.1000-9841.2011.04.0668]
　HUANG Yan-qin.Preparation of Biodiesel from Soybean Oil Catalyzed by New Solid Basic Catalyst[J].Soybean Science,2011,30(04):668-671.[doi:10.11861/j.issn.1000-9841.2011.04.0668]
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新型固体碱催化大豆油制备生物柴油的工艺研究

《大豆科学》[ISSN:1000-9841/CN:23-1227/S] 卷: 第30卷 期数: 2011年04期 页码: 668-671 栏目: 出版日期: 2011-08-25
Title:
Preparation of Biodiesel from Soybean Oil Catalyzed by New Solid Basic Catalyst
文章编号:
1000-9841（2011）04-0668-04
作者:
黄艳芹
新乡学院 化学与化工学院，河南 新乡 453003
Author(s):
HUANG Yan-qin
Department of Chemistry and Chemical Engineering,Xinxiang University,Xinxiang 453003,Henan,China
关键词:
新型固体碱催化剂; 大豆油; 生物柴油; 酯交换反应; 产率
Keywords:
New solid basic catalyst; Soybean oil; Biodiesel; Transesterification; Yield
分类号:
TQ645.1
DOI:
10.11861/j.issn.1000-9841.2011.04.0668
文献标志码:
A
摘要:
制备了新型固体碱催化剂KNO3/AlSBA-15，并以此催化大豆油与甲醇酯交换反应制备生物柴油，对其工艺条件进行了优化。结果表明：醇油物质的量比为12∶1，催化剂用量为大豆油质量的3%，反应温度65℃，反应时间4 h，生物柴油的产率可达81％以上。该催化剂对酯交换制备生物柴油具有较高的催化活性和良好的重复使用性。
Abstract:
New solid basic catalyst KNO3/AlSBA-15 was prepared.The transesterification of soybean oil and methanol to biodiesel catalyzed by KNO3/AlSBA-15 was studied.Optimization of processing parameters for biodiesel from soybean oil was researched.The results showed that the optimum reaction conditions were as following:molar ratio between methanol and soybean oil 12∶1,mass ratio of catalyst to soybean oil weight 3%,reaction temperature 65℃,reaction time 4 h.The yield of biodiesel reached 81% under the optimum reaction conditions.The catalyst for transesterification of biodiesel has higher catalytic activity and good reusability.

参考文献/References:

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备注/Memo

基金项目：河南省重点科技攻关资助项目（092102310184）；河南省自然科学研究计划资助项目（2008C480002）。

作者简介：黄艳芹（1966-），女，副教授，硕士，主要从事应用化学研究。E-mail: hyq200405@sohu.com。

更新日期/Last Update: 2014-08-15