[1]贺宏彬,柴庆平,王晓光.大豆蛋白乳液胶粘剂改性的研究[J].大豆科学,2008,27(05):891-894.[doi:10.11861/j.issn.1000-9841.2008.05.0891]
　HE Hong-bin,CHAI Qing-ping,WANG Xiao-guang.Modification of Soy Protein Emulsion Adhesive[J].Soybean Science,2008,27(05):891-894.[doi:10.11861/j.issn.1000-9841.2008.05.0891]
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大豆蛋白乳液胶粘剂改性的研究

《大豆科学》[ISSN:1000-9841/CN:23-1227/S] 卷: 第27卷 期数: 2008年05期 页码: 891-894 栏目: 出版日期: 2008-10-25
Title:
Modification of Soy Protein Emulsion Adhesive
文章编号:
1000-9841(2008)05-0891-04
作者:
贺宏彬; 柴庆平; 王晓光
辽宁林业职业技术学院，辽宁 沈阳 110101
Author(s):
HE Hong-bin; CHAI Qing-ping; WANG Xiao-guang
Liaoning Forestry Vocation-Technical College，Shenyang 110101，Liaoning，China
关键词:
大豆蛋白; 乳液胶粘剂; 改性
Keywords:
Soy protein; Emulsion adhesive; Modification
分类号:
Q816
DOI:
10.11861/j.issn.1000-9841.2008.05.0891
文献标志码:
A
摘要:
由于以石化原料合成的胶粘剂在生产和使用过程中会对环境带来不良影响，近年来采用可再生资源，如大豆蛋白合成环保胶粘剂已成为趋势。以尿素和亚硫酸钠改性大豆蛋白，与醋酸乙烯酯等复合单体在过硫酸铵引发下进行接枝共聚，合成了醋酸乙烯酯—大豆蛋白接枝共聚乳液胶粘剂。并通过金属盐、聚合物树脂、异氰酸酯、偶联剂与乳液共混改性的方法，研究了不同改性剂对乳液胶粘剂性能的影响。结果表明：采用金属盐改性制备的乳液胶粘剂具有良好的综合性能；异氰酸酯则应溶解于适当溶剂或使用其加成产物，以延长胶粘剂的适用期。
Abstract:
Adhesives made from petroleum chemicals have negative influence on environment in the process of manufacture and utilization，the environmental friendly adhesives which made by renewable natural resources，for example soy proteins，are becoming a new trend in recent years.In present investigation，emulsion adhesive by vinyl acetate-soy protein grafting copolymerization was synthesized using ammonium persulphate as an initiator，urea and sodium sulfite as a soy protein unfolding agent.Effect of different modifying agents such as mixed with metal salt，resin，isocyanate and resin acceptor was studied in experiment.The optimal modifying agents were metal salt and isocyanate，and they should be adjusted before added to emulsion adhesive to prolong the pot life.

参考文献/References:

[1]Zhong Z K，Sun X S，Fang X H,et al.Adhesion properties of soy protein with fiber cardboard[J] .Journal of the American Oil Chemists’Society，2001，78(1):37- 41.

[2] Kalapathy U，Hettiarachchy N S，Myers D,et al.Alkali-modified soy proteins effect of salts and disulfide bond cleavage on adhesion and viscosity[J] .Journal of the American Oil Chemists’Society,1996，73(8) :1063-1066.
[3] Kumar R，Choudhary V，Mishra S.Adhesives and plastics based on soy protein products[J ] .Industrial Crops and Products，2002，16 :155 -172.
[4]Cheng E，Sun X Z,Karr G S.Adhesive properties of modified soybean flour in wheat straw particleboard [J].Composites，2004，35 :297 -302.
[5]贺宏彬,王晓光,宋阳,等.醋酸乙烯酯-大豆蛋白接枝共聚乳液胶黏剂的研制[J].化学与黏合，2007，29(2):146-147,150.( He H B，Wang X G，Song Y，et al.Synthesis of emulsion adhesive by vinyl acetate-soy protein grafting copolymerization[J].Chemistry and Adhesion，2007，29(2):146-147,150.)
[6]郭梦麟.蛋白质木材胶黏剂（续）[J].林产工业,2005,32(5):3-7.(Guo M L.Protein-based wood adhesives(Continued)[J].China Forest Products Industry，2005,32(5):3-7.)
[7]张明珠,文志红，杨德超,等.聚醋酸乙烯乳液的改性的研究[J].化学与黏合，2002，4:157-158，167.(Zhang M Z，Wen Z H，Yang D C，et al.Modification of polyvinyl acetate emulsion[J].Chemistry and Adhesive，2002，4:157-158，167.)
[8]Li K C,Svetlana P，Geng X L.Investigation of Soy protein-kymene adhesive systems for wood composites[J ] .Journal of the American Oil Chemists’Society，2004,81(5):487 -491.
[9]Wang D H,Sun X Z.Low density particleboard from wheat staw and corn pith[J].Industrial Crops and Products,2002,15:43-50.

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备注/Memo

基金项目：辽宁省教育厅科学研究计划资助项目(05L197)。

作者简介：贺宏彬，男，副教授，从事木材胶粘剂的教学及研究工作。E-mail: hhblzy@yahoo.com.cn。

更新日期/Last Update: 2014-10-06