|Table of Contents|

Affecting Factors and Optimum Processing of Soybean Dregs Liquefaction in Phenol(PDF)

《大豆科学》[ISSN:1000-9841/CN:23-1227/S]

Issue:
2008年03期
Page:
501-504
Research Field:
Publishing date:

Info

Title:
Affecting Factors and Optimum Processing of Soybean Dregs Liquefaction in Phenol
Author(s):
ZHANG Tian-haoZHANG Qiu-huiZHAO Guang-jieHUANG Rong
College of Material Science and Technology,Beijing Forestry University,Beijing 100083,China
Keywords:
Soybean dregsPhenolLiquefactionAdhesive
PACS:
S565.1
DOI:
10.11861/j.issn.1000-9841.2008.03.0501
Abstract:
Recently liquefaction has been an important way of using biomass raw material.In order to enhance the additional value of soybean dregs,the single factor experiment and the orthogonal test has been used to study the soybean dregs phenol liquefaction craft,liquefaction production is prepared for wood adhesive.Under the effect of sulfuric acid catalytic,the soybean dregs could be liquefied well in the phenol.Among the four influncing factors of soybean dregs phenol liquefaction,catalyst had the most remarkable impact,then were the fluid ratio,the liquefaction time and the temperature.Within the scope of the experiment parameter that choiced,when the fluid ratio and the catalyst amount used were higher,the residual rate is lower,in other words the liquefied efficiency is higher.The optimal craft of soybean dregs phenol liquefaction was reacting at 150℃ for 1.5 h with 4:1of the phenol to soybean dregs mass ratio and 10% catalyst.Under this craft condition,the liquefation efficiency reached 97.3%.

References:

[1]栾建美,蒋蕴珍,张君慧,等.大豆蛋白作为胶粘剂应用的研究进展[J].中国油脂,2007,32(7):22-24.(Luan J M,Jiang Y Z,Zhang J H,et al.Progress of studies on modified soy protein adhesives[J].China Oils and Fats,2007,32(7):22-24.)

[2]Huang W N,Sun X Z.Adhesive properties of soy proteins modified by urea and guanidine hydrochloride[J].Journal of the American Oil Chemists’Society,2000,77:101-104.
[3]梁向晖,付时雨,林荣斌,等.大豆蛋白胶粘剂的化学改性研究进展[J].中国胶粘剂,2007,16(3):37-40.(Liang X H,Fu S Y,Lin R B,et al.Research progress of adhesives made from chemical modification of soy protein[J].China Adhesives,2007,16(3):37-40.)
[4]郑志锋,张宏健,顾继友.木质生物原料液化研究进展[J].云南化工,2004,31(5):27-30,34.(Zheng Z F,Zhang H J,Gu J Y.Research progress on woody biomass liquefaction[J].Yunnan Chemical Technology,2004,31(5):27-30,34.)
[5]李建章,周文瑞,赵俊杰,等.木材工业用酚醛树脂胶粘剂的快速固化研究[J].中国胶粘剂,2003,12(6):61-63.(Li J Z,Zhou W R,Zhao J J,et al.The progress of fast-setting phenol-formaldehyde resin wood adhesives[J].China Adhesives,2003,12(6):61-63.)
[6]揭淑俊.杉木苯酚液化物树脂的合成及应用[D].北京:北京林业大学,2007.(Jie S J.Synthesis and application of resins based on liquefied product from Chinese fir with phenol[D].Beijing:Beijing Forestry University,2007.)
[7]张求慧,赵广杰,陈金鹏.酸性催化剂对木材苯酚液化能力的影响[J].北京林业大学学报,2004,26(5):66-70.(Zhang Q H,Zhao G J,Chen J P.Effects of acid catalysts on liquefaction of wood in pbenol[J].Journal of Beijing Forestry University,2004,26(5):66-70.)
[8]Yao Y,Yoshioka M,Shiraishi N.Combined liquefaction of wood and starch in a polyethylene glycerin blended solvent[J].Journal of the Japan Wood Research Society,1993,39(8):930-938.
[9]Zhang Q H,Zhao G J,Jie S J.Effects of phosphoric acid on liquefaction of wood in phenol and optimum liquefaction processing[J].Forestry Studies in China,2004,6(3):50-54.
[10]Alma M H,Yoshioka M,Shiraishi N.Preparation of sulfuric acid-catalyzed phenolated wood resin[J].Wood Science and Technology,1996,32:297-308.
?[11]Lin L,Yao Y,Shiraishi N,et al.Liquefaction mechanism of β-0-4 lignin model compound lignin in the resence of phenol under acidcatalysts.PartⅡ.Reaction behavior and pathways[J].Holzforschung,2001,55:624-630.

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Last Update: 2014-10-08