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Response Surface Methodology to Optimize Production of Biodiesel from the Mixture of Soybean Oil Sediments and Soapstock(PDF)

《大豆科学》[ISSN:1000-9841/CN:23-1227/S]

Issue:
2008年03期
Page:
496-500，531
Research Field:
Publishing date:

Info

Title:
Response Surface Methodology to Optimize Production of Biodiesel from the Mixture of Soybean Oil Sediments and Soapstock
Author(s):
JIN Bo; ZHU Min; FAN Pei; ZHAO Jun-yi; YU Long-jiang
College of Life Science and Technology，Huazhong University of Science and Technology，Wuhan 430074，Hubei，China
Keywords:
Biodiesel; Response surface methodology; Oil sediments; Soapstock; Esterification reaction
PACS:
TQ641
DOI:
10.11861/j.issn.1000-9841.2008.03.0496
Abstract:
s the global fossil fuel deficiency and environmental degradation are becoming more and more serious，biodiesel is received increasing attention as an alternative，non-toxic，biodegradable and renewable diesel fuel.The production of biodiesel from the mixture of soybean oil sediments and soapstock was investigated in this work.In the first step，the mixture was extracted with ethyl ether and the mixture was divided into three phases.Ratio of the weight of mixture to the volume of solvent was 1:2(g ： mL)，and extracted at room temperature for 2 h.The organic top phase contained triglycerides and phosphatides was extracted withcooled acetone and the acetone insoluble(phosphatides)，a fairly high value by-product，was obtained，which could reuse and reduce the cost of biodiesel production.The triglycerides were also separated.In the second step，soap phase was then acidified with sulfuric acid to yield fatty acid.The mixed fatty acid was efficiently converted to methyl esters by acid-catalyzed esterification.The response surface methodology was used to optimize the esterification reaction conditions of fatty acid.Results showed the factors influence the esterification reaction was the molar ratio of methanol to oil，reaction temperature and reaction time，orderly.The molar ratio of methanol to oil and the reaction temperature had significant interaction.The optimal reaction were 5:1 methanol/ fatty acid(mol/mol) with 3% H2S04(wt%) reacted at 87℃ for 4.74 h，giving a maximum ester yield of 92.5%.

References:

[1]韩明汉，陈和，王金福，等.生物柴油制备技术的研究进展[J].石油化工，2006，35(12) ： 1119-1124.(Han M H，Chen H，Wang J F，et al.Advance in research for preparation of biodiesel oil [J].Petrochemical Technology，2006，35(12) ： 1119-1124.)

[2]马传国，司耀彬，侯华锋.皂脚制备生物柴油的研究[J].中国油脂，2006，31(4)：59-61.(Ma C G，Si Y B，Hou H F.Preparation of biodiesel with soapstock[J].China Oils and Fats，2006，31(4)：59-61.)
[3]郭宏珍，蒋惠亮，曾红舟.二步法催化高酸值大豆油制备生物柴油[J].大豆科学，2007，26(4)： 603-606.(Guo H Z，Jiang H L，Zeng H Z.Prepation of biodiedel from soybean oil with high acid value by two-step catalyzed process[J].Soybean Science，2007，26(4)： 603-606.)
[4]Canakci M，Gerpen J V.Biodiesel production from oils and fats with high free fatty acid[J].Transactions of the American Society of Agricultural Engineers，2001，44：1429-1436.
[5]Ghadge S V，Raheman H.Biodiesel production from mahua(Madhuca indica) oil having high free fatty acids[J].Biomass and Bioenergy，2005，28： 601-605.
[6]Meher L C，Sagar D V，Naik S N.Technical aspects of biodiesel production by transesterification-a review[J].Renewable and Sustainable Energy Reviews，2006，10： 248-268.
[7]Hass M J.Improving the economics of biodiesel production through the use of low value lipids as feedstocks： vegetable oil soapstock[J].Fuel Processing Technology，2005，86：1087-1096.
[8]Freedman B，Pryde E H，Mounts T L.Variables affecting the yields of fatty esters from transesterified vegetable oils[J].Journal of the American Oil Chemists Society，1984，61：1638-1643.
[9]Canakci M，Gerpen J V.Biodiesel production via acid catalysis[J].Transactions of the American Society of agricultural engineers，1999，42：1203-1210.
[10]Ma F，Hanna M A.Biodiesel production： a review[J].Bioresource Technology，1999，70： 1-15.
[11]Zullaikah S，Lai C C，Vali S R，et al.A two-step acid-catalyzed process for the production of biodiesel from rice bran oil[J].Bioresource Technology，2005，96：1889-1896.
[12]Haas M J，Bloomer S，Scott K.High-efficiency synthesis of fatty acid methyl esters from soapstock[J].Journal of American Oil Chemists Society，2000，77： 373-379.
[13]Haas M J，Michalski P J，Runyon S，et al.Production of FAME from acid oil，a byproduct of vegetable oil refining[J].Journal of American Oil Chemists Society，2003，80： 97-102.
[14]徐桂转，刘会丽，张百良.响应面法优化酶催化酯交换反应研究[J].化学工程，2007，35(3)： 63-67.(Xu G Z，Liu H L，Zhang B L.Optimization of lipase-catalyzed transesterification by response surface methodolog[J].Chemical Engineering，2007，35(3)： 63-67.)

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Last Update: 2014-10-08